![]() ![]() These effects result from the gas dissolving in the mucous membranes and saliva, forming a weak solution of carbonic acid. When inhaled at concentrations much higher than usual atmospheric levels, it can produce a sour taste in the mouth and a stinging sensation in the nose and throat. ![]() In its solid state, carbon dioxide is commonly called dry ice.įor more details on this topic, see Carbon dioxide (data page).Carbon dioxide is a colorless, odorless gas. Inorganic carbon dioxide is output by volcanoes and other geothermal processes such as hot springs.Ĭarbon dioxide is an important greenhouse gas because it transmits visible light but absorbs strongly in the infrared.Ĭarbon dioxide has no liquid state at pressures below 5.1 atm, but is a solid at temperatures below -78 ☌. Carbon dioxide is generated as a byproduct of the combustion of fossil fuels or vegetable matter, among other chemical processes. It is, therefore, a major component of the carbon cycle. Ĭarbon dioxide is produced by all animals, plants, fungi and microorganisms during respiration and is used by plants during photosynthesis to make sugars which may either be consumed again in respiration or used as the raw material for plant growth. Carbon dioxide's chemical formula is CO 2. ![]() It is currently at a globally averaged concentration of approximately 383 ppm by volume in the Earth's atmosphere, although this varies both by location and time. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state. All rights reserved.Carbonic acid gas carbonic anhydride dry ice (solid)Ĭarbon monoxide carbon suboxide dicarbon monoxide carbon trioxideĮxcept where noted otherwise, data are given for materials in their standard state (at 25 ☌, 100 kPa) Infobox disclaimer and referencesĬarbon dioxide is a chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom. On behalf of the United States of America. Shall not be liable for any damage that may result fromįor NIST Standard Reference Data products. However, NIST makes no warranties to that effect, and NIST Uses its best efforts to deliver a high quality copy of theĭatabase and to verify that the data contained therein haveīeen selected on the basis of sound scientific judgment. The National Institute of Standards and Technology (NIST) Data from NIST Standard Reference Database 69:.Go To: Top, Reaction thermochemistry data, ReferencesĮnthalpy of reaction at standard conditions Kinetics and technological conditions for the synthesis of dimethyl carbonate,Ĭhem. Structural effects on rates and equilibria. Determination of the enthalpies of hydrolysis of some polyoxygenated hydrocarbons, Ī microprocessor-controlled system for precise measurement of temperature changes. Go To: Top, Reaction thermochemistry data, Notes Reaction search pages in place of the enumerated reactionīy formula: C 5H 12O 4 + H 2O = C 3H 6O 3 + 2 CH 4O Quantityīy formula: C 4H 6O 3 + 2 CH 4O = C 3H 8O 2 + C 3H 6O 3 Quantity Secretary of Commerce on behalf of the U.S.A.ĭata compiled by: Hussein Y. Your institution may already be a subscriber.įollow the links above to find out more about the dataīy the U.S. With the development of data collections included in The purpose of the fee is to recover costs associated NIST subscription sites provide data under theĭata Program, but require an annual fee to access. NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data).X-ray Photoelectron Spectroscopy Database, version 4.1.Use this link for bookmarking this species This structure is also available as a 2d Mol file IUPAC Standard InChIKey: IEJIGPNLZYLLBP-UHFFFAOYSA-N Copy. ![]()
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![]() The mechanics of Jump King are as simple as they are frustrating. While the concept of the game is the same as Getting Over It, Jump King differs greatly in terms of mechanics and aesthetic design. Jump King came out back in early 2019 and quickly rose in popularity due to the streaming community yet again. Next up on this list of difficult games we have Jump King. “Take up the challenge and face true high-stakes platforming in Jump King! Struggle upwards in search of the Smoking Hot Babe of legend, but explore with care a single missed jump could lead to a long fall back down.“ Image courtesy of As you can see from the record, however, there is plenty of room to improve your skills and consequently your time! I’d estimate that a first time player’s run will take somewhere in the realm of six to ten hours, depending on how often you fall and your experience with games like this one. ![]() While this is a pleasure to watch, replicating such an act is nearly impossible. The current record is set at a mind-boggling one minute and 24 seconds by Lockness06. From this, many people have taken up the game as a speedrunning game. After a couple of game completions, you will get used to the mechanics and can constantly improve your time. The first playthrough is often the best in terms of player experience as the narration provided often mocks the player and insists on making them quit. Even better (or worse), these big jumps happen to overhang a massive gap in the map meaning that a missed jump often results in losing a huge chunk of progress through the map. This makes for some close calls on some of the biggest jumps in the game. There are also multiple parts of the map that require the player to use the sledgehammer as a jumping tool by placing it beneath them and pushing in the opposite direction. This seems like a simple concept, but is much more difficult to do in practice. ![]() Utilizing your mouse, you control the sledgehammer to pull yourself up and across the terrain. Your character is a man in a cauldron wielding a sledgehammer that you will use to navigate the terrain. The controls of Getting Over It are extremely simple. After all, everyone loves watching their favorite streamer rage when they fall and lose all of their progress they have made. Getting Over It came out back in 2017 and quickly gained traction amongst the streaming community. There is no better place to start out with a list of Foddy style games than the original inspiration for the genre. “A game I made for a certain kind of person. ![]() Getting Over It with Bennet Foddy - $7.99 Now that you have a good idea of what a Foddy style game is, let’s get into the hardest games of all time, all playable through the Steam marketplace: Above all else, games within this genre require a level of patience and commitment that no other genre can demand. There are other attributes typical of a Foddy game, but that mechanic is the core feature that defines the genre. ![]() It is meant to be a game in which the player can not mess up even a single jump or they fall back down a significant portion of the map, sometimes even all the way to the beginning. Even worse, there are no checkpoints along the way. Falling back down the map is a common setback players will face. Typically, Foddy games feature a frustrating style of gameplay consisting of climbing towards the top of the map. The term ‘Foddy’ describes a slightly wider genre matching the style of games created by Bennet Foddy (the first feature on this list). Before continuing on with this list of difficult games, let me set the stage as to how this genre of ‘Foddy games’ originated and exactly what it entails. Both attitudes see video games as a source of satisfaction, it is only the process in which they achieve said satisfaction that differs. Others look at video games as a potential source of challenge, basking in the suffering of difficulty. Many people turn towards video games to escape reality, even if only for a brief moment, and enjoy a brief break from the stresses of the modern world. ![]() ![]() You can also tap Tell us what’s happening to let Apple Support pinpoint the problem and offer you helpful solutions. Select your issue from the list of categories on the list.Under My Devices, tap the device you’re having issues with. ![]() The app contains resources about your Apple device and lets you contact Apple Support directly through your device.įirst, be sure that the app is installed on your device if not, you can always download the Apple Support app from the App Store. The easiest and quickest way to book an appointment at a nearby Genius Bar is embedded within your device – the Apple Support app. Schedule a Genius Bar appointment using the Support app on iPhone or iPad However, simple repairs like battery replacements and other minor replacements can be done in-store, and your device is returned to you on the same day. Sometimes, the Genius Bar needs to send your device off, especially if a more extensive repair is necessary - like a screen repair. Note: Not all kinds of repairs can be handled in-store. They’re skilled to help with all your software and hardware concerns and assist you with your issues. The people staffing Apple’s Genius Bar outlets are trained at the Apple corporate headquarters. The issue could be related to an Apple device or an Apple service you’re using – say, an Apple TV subscription. It handles troubleshooting and repairs for Apple products and other services. The Genius Bar is a support service found within Apple Stores. What can Apple’s Genius Bar help you with?
![]() Ella would not respond to these for months (some she NEVER replied to!), making booking vendors very challenging.Ģ. We complied and would send over approval emails. Later we were scolded that the houdini needed to "sign off" on vendors. We were told we have full "freedom of choice" for all vendors. Like most of LA, there are severe noise ordinances, and sound is very carefully regulated.ġ. Also there are truck height limitations that also make rentals a challenge. Logistical challenge: difficult to load in/out rentals, only one street so we had to stage who came when. It’s unpleasant enough that we did not want to sleep in the master bedroom or leave my wedding dress there overnight in case it took on the smell. House is dated: A/C didn’t work for some time when we were there, and the two bottom bedrooms still smell STRONGLY of smoke (there was a fire ~2 years ago?). Gardens are incredibly well kept and absolutely gorgeous - definitely the reason for booking. The beauty of the venue is NOT worth the stress. The mansion is home to three full bedrooms and can comfortably sleep eight people, although sofas and roll-away beds are available for larger parties.Įlt any kind of hospitality on par with a venue of this caliber. ![]() You're also invited to stay here for your honeymoon, taking advantage of this iconic area. Tables and chairs can be supplied, as well as a dance floor for 75 people. Stunning photo backdrops can be found near the waterfall and natural spring pond. This includes romantic gazebos with views of the canyon, a landscaped lawn, and plenty of private gardens. The beautiful grounds offer countless spaces where you can celebrate your love story. There is also on-site parking for 80 cars. The Houdini Estate is perfect for grand gatherings, and can comfortably accommodate up to 1,000 guests. Guests from out of town will love the glamorous environment, with Beverly Hills and the Sunset Strip just minutes away. ![]() The estate was then lovingly restored and renovated, combining the mystery of Houdini's life with luxurious modern amenities. His wife, Bess, lived here for years after his death. Houdini used this property as an escape, as well as somewhere to rehearse his daring tricks. The grounds are dotted with caves and hidden tunnels, as well as beautiful terraced gardens. Walker, a friend of iconic magician Harry Houdini. ![]() The mansion was built in the Edwardian style by owner Ralph M. Nestled in Laurel Canyon, guests will remember a celebration in The Houdini Estate for years to come. You are also invited to celebrate showers, proposals, and vow renewals here. Nestled in the Hollywood Hills, this five-acre property offers an unforgettable setting for your milestone day. The Houdini Estate, located in Los Angeles, CA, is a historic wedding venue. ![]() ![]() However, the feature did not work as intended, so it's not surprising that the company ultimately ditched it for good. Samsung actually debuted a similar feature in the Galaxy S3 back in 2012 called Smart Rotation. To ensure that all this processing does not delay the actual auto-rotation, Google has "optimized the animation and redrawing and added an ML-driven gesture-detection algorithm" All these improvements will reduce the auto-rotate latency by 25 percent. You can do this by using apps such as Sensors Multitool and Sensors Test. First, run some tests to see if your sensors are indeed malfunctioning. Apart from this, the Private Compute Core is also used by Google to power the Live Caption and Smart Reply features in Android 12. Another reason why your Android device is not auto rotating is either because the G-sensor or the accelerometer is malfunctioning. Right now I am disabling the accelerometer rotation system setting and setting my preferred orientation. They work even if an app explicitly wants to be viewed in another orientation. The entire processing for this feature happens in Android 12's Private Compute Core, so the photos are never sent to any server or stored on the device. There are a number of apps that are able to force screen rotation. Google is now using the same approach to deliver a better user experience when using auto-rotate. Tap Per App rotation settings, choose the apps whose settings you wish to alter, then change their settings.Android OEMs like Samsung already use the front camera to keep the display on when you are looking at it.If you dont touch the override button, the screen wont rotate. In the menu, make sure Rotation Control and Per App Settings are enabled. Android 10 has a 'quick' override for the screen orientation (not just on Samsungs - its on all android 10 devices) I assume you are touching the small icon that appears in the nav bar area when you hold your phone in landscape.Apparently tablets were not envisioned for use while lying sideways. This is just so Rotation Control can be notified when an app is launched and can be displayed over other apps. When you disable auto-rotation, the screen will always remain in a landscape mode. After installing the app, you'll be asked to enable several permissions.The app is $2.99 on Google Play, but a free trial version can be downloaded and used for two days so that you check that it works for your needs.ĭownload: Rotation Control (Free trial) | Rotation Control Pro ($2.99) Rather than simply being a constant overlay, or an app you need to open whenever you want to reorient your screen, Rotation Control Pro allows you to automate screen rotation settings for every individual app. If you want to disable screen rotation for a select few apps, or enable rotation for apps that don't normally allow it, Rotation Control Pro can do just that. I believe it is called Smart Auto-Rotate. I do recall there being an app which allows setting auto-rotate on and off on a per-app basis. How can I turn off the rotation for this fragment Ive read always how to do it for a whole activity but for the rest of the activity this runs in I want to keep the auto rotation. What I have settled for is turning off auto-rotate, and only using it for apps where I really need rotation. It works fine, but when I rotate my smartphone, the picture also rotates and gets scaled very ugly sothat its height is now its actual width and so on. How to Install and Use Rotation Control on Your Android Device I have searched for the same thing, and unfortunately, have not come up with much of anything. How To Change Screen Orientation on Android: Way 1 As we discussed earlier, now we'll learn how to enable and disable screen rotation on Android using the in-built functions. Android ImageView Displaying Rotated Images Although Source Is Not Rotated. Auto rotate is on in settings & apps that are allowed to auto rotate are doing so. Android Imageview displays old bitmap after screen rotates. Disable Auto Rotate after select large image from gallery in android. This means you can lock Twitter in portrait, force Instagram into landscape, and allow YouTube to switch freely between both. Requirements Android Phone or Tablet (v2.3 or above). With the launch of the Android 12 Developer Preview seemingly around the corner, we’ve learned that Pixel phones may be gaining a new face-based option for Auto-Rotate. In my android application i am loading image from device gallery.In that. Beware seems the button marked 4 only appears for few seconds. To rotate, Virtual sensors option can be utilized as follows. Rotation Control Pro allows you to manage individual screen orientation settings for all of your apps. Disable the docking and may be open in Window mode to keep emulator window separate from the main IDE as shown below. ![]() ![]() ![]() Because you are only allowed to deduct the business use of your car, you can only deduct those 11,000 miles. Of those, 11,000 were business miles driven as a rideshare driver for Uber or Lyft. You own a car and drove a total of 18,000 miles for the year. Additionally, you can only deduct the business miles, not the personal miles, from the use of a car. So, you cannot deduct these expenses separately. The IRS mileage rate for 2019 of 58 cents per mile is supposed to be high enough that it accounts for these expenses. Maintenance and repairs (e.g., oil, tires, etc.).However, it prevents you from deducting other misc expenses that you put into your car, including: Opting to use this mileage deduction could be useful if you put a lot of miles on the car. This is the standard mileage deduction for all independent contractors. The IRS mileage rate for 2019 is 58 cents per mile. You track your business mileage and then multiply the total number by the rate set by the IRS for that tax year. The standard mileage rate lumps ordinary expenses together and allows you to deduct a single price per mile. ![]() You’ll also find some industry-specific expenses, which could impact Uber taxes and other similar self-employment taxes. Whichever you choose, both are due April 15th along with your annual tax return.īelow, you’ll find a breakdown of common expenses and tax deductions for independent contractors. If you have less than $5,000 in claims, you may be able to use Schedule C-EZ. You’ll likely list the majority of your deductions in Part II of your Schedule C (Form 1040). When you file your tax form for the year, you’ll want to complete a Schedule C. Doing so can net you a significant reduction come tax time. Thus, when working as an independent contractor, it’s vital that you track your business expenses. Because of this, the Internal Revenue Service allows self-employed professionals to claim deductions for work-related expenses, which helps lower their tax burden. Self-employed workers are unique because they don’t have taxes withheld from their paychecks like traditional employees. Rideshare service drivers, like Lyft and Uber drivers.The IRS defines independent contractors as those who “offer their services to the general public” and whose services are not controlled by an employer. Self-employment tax can come as a shock, especially when filing your first tax return as an independent contractor. As an independent contractor, you’re responsible for paying self-employment tax on any income you make. ![]() ![]() The selected string will play every 2 seconds so you can concentrate on your instrument.
![]() ![]() While passionately traveling the globe to cover everything from automobiles to culinary scenes, celebrity profiles, sports, hotel destinations, art, and what he terms “the world’s best beverage,” Ale has contributed to more than 30 magazines and websites combined. This project with New Belgium also spawned his initiative, BrewGether, which raises funds to support nonprofits embracing the same mission as Piano Keys.Īle proudly owns AllWays Open Creative Solutions, an agency specializing in creative direction, logo design, branding, web design, video production, photography, consulting, and social media.Īlthough a native New Yorker, Ale proudly calls Atlanta his home.įollow Ale’s globetrotting adventures on his captivating Instagram ( Malcolm Byron aka Ale Sharpton is a world-renowned beer authority, award-winning journalist, blogger ( ), photographer, event planner, host, speaker and beer judge to name a few of his roles. In a collaboration going on six years with brewing giant New Belgium, Ale has produced a beer he conceptualized called Piano Keys-a chocolate vanilla imperial stout-geared to support diversity and racial equality. Forbes, Smithsonian Institution, UNTAPPD, Good Beer Hunting, and numerous others have showcased Ale’s accomplishments. His current media outlets include USAToday,, Craft Beer & Brewing,, ,, James Beard Foundation, Atlanta Magazine, and others.Īlong with being featured in various publications, on the web, radio, podcasts, television, beer fests, conferences, and ongoing Cruisin’ For A Brewsin’ video series, Ale utilizes his Cornell University School of Hotel Administration education and vast work experience to consult in the culinary industry as well. Read Moreĭennis Malcolm Byron aka Ale Sharpton is a world-renowned beer authority, award-winning journalist, blogger ( ), photographer, event planner, host, speaker and beer judge to name a few of his roles. He lives in Chicago, Illinois, near Wrigley Field, and is available for speaking appearances and guided tastings.ĭennis Malcolm Byron aka Ale Sharpton is a. ![]() ![]() In 2012, Cowdery was cited by the 6th Circuit Court of Appeals as an expert on the history and marketing of American whiskey in Maker's Mark v Diageo. Musicians, and he was a contributor to 1001 Whiskies You Must Taste Before You Die (2012). He also wrote the ‘Bourbon’ article in The New Encyclopedia of Southern Culture, Volume 7, Foodways (2007). Hirsch Reserve Straight Bourbon Whiskey, Distilled in the Spring of 1974 (2012), and Bourbon, Straight: The Uncut and Unfiltered Story of American Whiskey (2004). Other books include Blues Legends (1995), 20 profiles of notable blues ‘Chuck’ Cowdery “the dean of American whiskey journalism.” He is a Kentucky Colonel, a member of the Kentucky Bourbon Hall of Fame (2009), the producer/director/writer of the public television documentary "Made and Bottled in Kentucky" (1992), a regular contributor to Whisky Advocate Magazine and Bourbon+ Magazine, and the editor and publisher of The Bourbon Country Reader, the oldest publication dedicated exclusively to American whiskey.Ĭowdery is the author of Bourbon, Strange: Surprising Stories of American Whiskey (2014), The Best Bourbon You’ll Never Taste. ![]() ![]() ![]() Available with front- or all-wheel drive, it competes against the Honda CR-V, Toyota RAV4 and Hyundai Tucson. Whichever model you choose, know that Chevrolet Equinox comes packed with innovative technology and safety features that will keep you and your family safe on the road.This five-seat compact SUV is powered by a 170-horsepower, turbocharged 1.5-liter four-cylinder engine paired with a six-speed automatic transmission. If you want something with even more bells and whistles, the RS may be a better fit. If you're looking for a car that offers excellent performance and an impressive set of standard features, the LT model might be perfect. Valley Chevy Dealers would like to help make your decision easier. With so many options on the market, it can be hard to decide which vehicle is right for you. Visit Valley Chevy Dealers to Test Drive a New Chevy in Phoenix Today! According to both National Highway Traffic Safety Administration and the Insurance Institute for Highway Safety, the Chevrolet Equinox received a top scores rating in all the crash tests. Safety is one area where you can't go wrong with either of the models. The RS model also has an automatic heated steering wheel, which is a great feature, especially in cold climates. On the other hand, the 2022 Equinox RS model takes it up a notch by adding the following features: The LED daytime running lamps are also a great addition to the safety roster. As mentioned earlier, the LS standard safety features include: Lane change alert with side blind zone alertīoth the Equinox LT and RS don't disappoint when it comes to safety.You can find the following features in the RS Driving Confidence Package: It also has wireless charging and a 4G LTE Wi-Fi® hotspot as standard features. On the other hand, the RS model offers an 8-inch touchscreen display with the same Infotainment 3 System and audio system. ![]() Some of the available LT confidence & convenience package include: The integration of Apple CarPlay® and Android Auto™ comes as a relief for all the tech-savvy customers out there. The 2022 Equinox LT model comes standard with Chevrolet Infotainment 3 System, a 7-inch touchscreen display, and a 6-speaker audio system. A lot sets the two trims apart from the technology to the safety features. RS: Standard Featuresĭespite 2022 Equinox LT and RS sharing the same drivetrain, some stark differences in their standard features make each model stand out. As compared to other compact crossovers in its class, it is safe to say that the 2022 Chevrolet Equinox LT and RS offer one of the best fuel economy ratings. Whether you choose a front-wheel-drive or all-wheel drive, the Chevrolet Equinox LT and RS earn above 25 mpg on combined EPA ratings. The ride is butter smooth, and the cabin is well insulated from road noise. Both trims offer a well-composed and fine-tuned handling that is hard to come by in this segment. The all-wheel-drive system is optional on both trims.Ĭruising through Phoenix, AZ, has never been this effortless and comfortable. It pairs a 6-speed automatic transmission to give out 170 horsepower and 203 lb-ft of torque. RS: PerformanceĢ022 Chevrolet Equinox LT and RS are powered by a standard turbocharged and intercooled DOHC 1.5-liter inline-4 engine. So, if you're torn between the two, this read will help clear the air. Fortunately, the LT and RS trims sit in the middle of the lineup, which gives you more features without going overboard and spending too much.īut how do the two trims compare? Our experts at Valley Chevy, Phoenix, AZ, put together a comprehensive head-to-head guide of Chevrolet Equinox LT vs. It comes in four trim levels: L, LS, LT, and Premier. The new 2022 Chevrolet Equinox falls under the compact SUV category. If you're in the market for a spacious and decent fuel economy SUV, Chevrolet Equinox is a solid choice. ![]() ![]() ![]() Take the next step forward in the story of The Talos Principle in a thought-provoking, character-driven interactive story with multiple endings penned by returning writers Jonas Kyratzes (The Eternal Cylinder, Clash: Artifacts of Chaos) and Tom Jubert (The Swapper, Subnautica), joined by Verena Kyratzes (The Hand of Merlin, Serious Sam 4).Įxplore more than a dozen all-new environments, from a city on the brink of a paradigm shift to the varied landscapes of a mysterious island that holds the keys to the future. A variety of new abilities, such as gravity manipulation and mind transference, join the established mechanics of the original Talos Principle, creating a fresh but familiar experience. Finish the game without solving every puzzle, or pursue the rewards of complete mastery. Solve a wide array of puzzles with varying difficulty levels, including clever metapuzzles and highly challenging Gold puzzles. ![]() The broken promise of a better tomorrow, the fear of repeating humankind’s mistakes, faith in reason or renouncing humanity altogether - the choices you make and the sides you take will determine the course of events. The more you discover, the more you will be confronted with questions about the nature of the cosmos and the purpose of civilization. The Talos Principle 2 is a thought-provoking first-person puzzle experience that greatly expands on the first game's philosophical themes and stunning environments with increasingly mind-bending challenges.īorn into a new world where biological humanity is extinct but human culture lives on in a city of robots, you find yourself swept up in a mind-bending adventure involving a mysterious megastructure hiding enormous powers. ![]() |
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